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A Study on the Electro-and-bioelectro-deposition of Heavy Metals in Municipal Solid Waste Incinerator Fly Ash
FENG Zhendong, LEI Tao, ZHANG Shanfa, ZHANG Lijuan, DING Lingyun, TAO Huchun
Acta Scientiarum Naturalium Universitatis Pekinensis    2022, 58 (4): 673-679.   DOI: 10.13209/j.0479-8023.2022.034
Abstract421)   HTML    PDF(pc) (9916KB)(147)       Save
The contents and leaching concentrations of heavy metals from municipal solid waste incinerator (MSWI) fly ash were investigated in Shenzhen. Targeting at Cu, Pb and Zn as the key heavy metals, aqueous solutions containing Cu(II), Pb(II) and Zn(II) of 100 mg/L, 200 mg/L and 300 mg/L were synthesized to test the feasibility and efficiency of electro-and-bioelectro-deposition of heavy metals. In a bio-electrochemical system (BES), the removal and recovery efficiency of Cu(II) was >98%. In the subsequent electro-deposition reactor (ER), the concentrations of Pb(II) and Zn(II) were decreased from 200 and 300 mg/L to 23.5±1.1 and 4.3±0.2 mg/L with external voltage of 1.5 and 2.5 V, respectively. Energy consumption analysis revealed that extra electricity of 16.55 kWh was generated by 1 kg Cu(II) reduction in BES, while electricity of 60.91 kWh and 114.27 kWh were consumed by 1 kg Pb(II) and Zn(II) treatment in ER, and the heavy metal ions were reducted to free elements, oxides and salts. These results suggest that a combined BES and ER technology has advantages in metal recovery and energy saving. 
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Urgency Classification of Beijing Ecological Security Pattern Protection
YU Chaoyue, WANG Chenxu, FENG Zhe, WU Kening, ZHAO Huafu
Acta Scientiarum Naturalium Universitatis Pekinensis    2020, 56 (6): 1047-1055.   DOI: 10.13209/j.0479-8023.2020.093
Abstract652)   HTML    PDF(pc) (11938KB)(208)       Save
Taking Beijing as an example, the granularity back-calculation method and the landscape connectivity index were combined to identify important ecological land. The neighborhood analysis was adopted to construct the ecological resistance surface, whereas the minimum cumulative resistance model was used to construct the ecological security pattern. The probability of land expansion calculated through an artificial neural network was used to classify the ecological security pattern of construction. The results show that the important ecological land area of Beijing is 6488.53 km2, mainly distributed in the mountainous areas of western and northeastern Beijing, and a small part is located in the southeast plain area. The primary protection ecological land area is 4482.48 km2, mainly distributed in the northwest and southwest. The secondary protection ecological land area is 1338.27 km2, which is mainly distributed in the western suburbs, the suburban plains in the southwest and the plains in the southeast. The third-level protection ecological land area is 669.77 km2, mainly distributed in the north-central and southeast plains. The important ecological corridor is 2410.47 km long and is distributed in the outer suburbs and urban-rural junction. Among them, the length of the first-class ecological corridor is 1477.63 km, mainly distributed in the mountainous areas of the northwest and southwestern suburbs; the secondary ecological corridor is 390.91 km, which is mainly distributed near the ecological land of the outer suburb plain; the third-level ecological corridor is 541.93 km, mainly distributed in the surrounding area of the city center, surrounded by the central city.
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Study on the Catalytic Oxidation of Rhodamine B by Nanoporous Carbon Materials Loaded with Zero Valence Copper
WANG Aide, FENG Zhendong, QIN Dayu, ZHANG Lijuan, ZHU Lili, ZHANG Shanfa, TAO Huchun
Acta Scientiarum Naturalium Universitatis Pekinensis    2020, 56 (4): 703-709.   DOI: 10.13209/j.0479-8023.2020.033
Abstract1150)   HTML    PDF(pc) (4102KB)(136)       Save
Nanoporous carbon material loaded with zero-valent copper NPC@Cu was synthesized by one-step carbonization method using copper-based MOF (HKUST-1, [Cu3(BTC)2], BTC as 1,3,5-benzenetricarboxylic acid) as template. With NPC@Cu as catalyst, peroxymonosulfatesulfate (PMS) was activated as oxidant to treat simulated azo dye wastewater by heterogeneous catalytic oxidation at ambient pressure and room temperature. The catalysts were characterized by electron microscopy (SEM), X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS), etc. The effect of degradation efficiency of the catalyst dosage, oxidant dosage and initial pH during the reaction were studied. The experimental results showed that the degradation rate of 0.10 mmol/L RhB can reach 100% after 45 minutes of reaction at a catalyst dosage of 0.1 g/L, a PMS concentration of 2.00 mmol/L and a initial pH of 7. Through the free radical trapping experiment, it proved that there are two free radicals in the system—SO4·and ·OH, and NPC@Cu is a catalytic material with good catalytic performance.
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Study on Farmers’ Satisfaction with Land Consolidation Performance from the Perspective of Livelihood Capital: A Case Study of Ranyi Town, Sichuan Province
CHEN Tianqian, FENG Zhe, CUI Yongliang, ZHAO Huafu
Acta Scientiarum Naturalium Universitatis Pekinensis    2020, 56 (2): 365-372.   DOI: 10.13209/j.0479-8023.2020.007
Abstract659)   HTML    PDF(pc) (1111KB)(141)       Save
In order to evaluate the satisfaction of land consolidation performance, Ranyi Town in Qionglai City, Sichuan Province was selected as the study area, and the data were obtained through questionnaires and interviews. According to the occupation, the farmers were divided into four types: pure agriculture, agriculturebased, non-agricultural-based and non-agricultural. The livelihood capital estimation table was constructed from five aspects: human capital, natural capital, physical capital, financial capital and social capital to evaluate the current status of the livelihood capital of farmers with different livelihood types in the land consolidation area. Based on the calculation results, the impact of land consolidation on farmer satisfaction was investigated, and the Probit model was used to analyze the influencing factors of satisfaction. The results show that the farmer’s livelihood capital is slightly out of balance, the social capital and material capital value are higher, and the financial capital and human capital value are lower. Farmers generally have higher satisfaction with land consolidation projects. Factors such as natural capital, physical capital, social capital, and income sources have a positive impact on satisfaction; education, financial capital, and livelihood activities have a negative impact on non-agricultural farmers’ satisfaction.
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Assessing the Vulnerability of Ecosystem Services of Beijing-Tianjin-Hebei Area Based on Radial Basis Function Network
LIU Jinlong,MA Cheng,WANG Yang,FENG Zhe,LI Shuangcheng
Acta Scientiarum Naturalium Universitatis Pekinensis   
Abstract614)      PDF(pc) (2038KB)(550)       Save
The authors put forward the concept of vulnerability of ecosystem services, and carries a case study in Beijing-Tianjin-Hebei Area. The changes of ecosystem services were calculated from 2001 to 2009 in this region, and radial basis function network was used to assess the potential impacts of ecosystem services to land use change and the adaptive capacity of human-beings based on the 9 training data chosen from 164 counties. The results show that the average ecosystem services value of study area has declined 184.36 yuan/ha from 2001 to 2009, and the positive potential impacts of ecosystem services to future land use change declines from southeast to northwest, and the middle shows the least; the districts near big cities such as Beijing, Tianjin and Tangshan have the best adaptive capacity, which has a positive correlation with GDP; and by integrating potential impacts and adaptive capacity, the study gives the spatial pattern of the vulnerability of ecosystem services: the districts near Bohai Sea turn out to be the least vulnerable; the plain in the southeast and mountains in the northwest are worse; and the districts near Taihang Mountains in the west are the most vulnerable. Of all the residents living in this region, 92.4% range between 2 to 4 in the classification of vulnerability.
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